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935 Ceramic Coating
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Revision date: 3/1/2023 Revision: 5 SAFETY DATA SHEET Ceramic Coating According to Appendix D, OSHA Hazard Communication Standard 29 CFR ?1910.1200 1. Identification Product identifier Product name Ceramic Coating Product number 935 Recommended use of the chemical and restrictions on use Application Car maintenance product. Uses advised against No specific uses advised against are identified. Details of the supplier of the safety data sheet Manufacturer 3D International LLC 20724 Centre Pointe Pkwy Unit 1 Santa Clarita, CA 91350 888-999-7627 Emergency telephone number Emergency telephone CHEMTREC 1-800-424-9300 (US and Canada) 2. Hazard(s) identification Classification of the substance or mixture Physical hazards Flam. Liq. 3 - H226 Health hazards Skin Irrit. 2 - H315 Eye Irrit. 2A - H319 Repr. 2 - H361 STOT SE 3 - H335 STOT RE 2 - H373 Environmental hazards Not Classified Label elements Hazard symbols Signal word Warning Hazard statements H226 Flammable liquid and vapor. H315 Causes skin irritation. H319 Causes serious eye irritation. H361 Suspected of damaging fertility or the unborn child. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure. 1/11 Revision date: 3/1/2023 Revision: 5 Ceramic Coating Precautionary statements P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, sparks, open flames and hot surfaces. No smoking. P240 Ground/ bond container and receiving equipment. P241 Use explosion-proof electrical equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P260 Do not breathe vapor/ spray. P261 Avoid breathing vapor/ spray. P264 Wash contaminated skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P302+P352 If on skin: Wash with plenty of water. P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304+P340 If inhaled: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 If exposed or concerned: Get medical advice/ attention. P312 Call a poison center/ doctor if you feel unwell. P314 Get medical advice/ attention if you feel unwell. P321 Specific treatment (see medical advice on this label). P332+P313 If skin irritation occurs: Get medical advice/ attention. P337+P313 If eye irritation persists: Get medical advice/ attention. P362+P364 Take off contaminated clothing and wash it before reuse. P370+P378 In case of fire: Use foam, carbon dioxide, dry powder or water fog to extinguish. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/ container in accordance with national regulations. Contains Parachlorobenzotrifluoride, Siloxanes and Silicones Other hazards This product does not contain any substances classified as PBT or vPvB. 3. Composition/information on ingredients Mixtures Parachlorobenzotrifluoride 60-100% CAS number: 98-56-6 Classification Flam. Liq. 3 - H226 Skin Irrit. 2 - H315 Eye Irrit. 2A - H319 STOT SE 3 - H335 Siloxanes and Silicones 5-10% CAS number: 68037-85-4 Classification Flam. Liq. 4 - H227 Repr. 2 - H361 STOT RE 2 - H373 2/11 Revision date: 3/1/2023 Revision: 5 Ceramic Coating methyl acetate 5-10% CAS number: 79-20-9 Classification Flam. Liq. 2 - H225 Eye Irrit. 2 - H319 STOT SE 3 - H336 toluene < 0.1% CAS number: 108-88-3 Classification Flam. Liq. 2 - H225 Skin Irrit. 2 - H315 Repr. 2 - H361d STOT SE 3 - H336 STOT RE 2 - H373 Asp. Tox. 1 - H304 The full text for all hazard statements is displayed in Section 16. Composition comments Components listed, if any, are present above their levels of disclosure. Ingredient notes The exact percentage/concentration is withheld as a trade secret in accordance with 29 CFR 1910.1200. 4. First-aid measures Description of first aid measures General information Get medical attention if any discomfort continues. Show this Safety Data Sheet to the medical personnel. Inhalation Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Maintain an open airway. Loosen tight clothing such as collar, tie or belt. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen. Get medical attention. Place unconscious person on their side in the recovery position and ensure breathing can take place. Ingestion Rinse mouth thoroughly with water. Give a few small glasses of water or milk to drink. Stop if the affected person feels sick as vomiting may be dangerous. Never give anything by mouth to an unconscious person. Place unconscious person on their side in the recovery position and ensure breathing can take place. Keep affected person under observation. Get medical attention if symptoms are severe or persist. Skin Contact Rinse with water. Eye contact Rinse with water. Do not rub eye. Remove any contact lenses and open eyelids wide apart. Get medical attention if any discomfort continues. Protection of first aiders First aid personnel should wear appropriate protective equipment during any rescue. Most important symptoms and effects, both acute and delayed General information The severity of the symptoms described will vary dependent on the concentration and the length of exposure. Inhalation A single exposure may cause the following adverse effects: Irritation of nose, throat and airway. Difficulty in breathing. Coughing. Ingestion May cause irritation. Skin contact Redness. Irritating to skin. Eye contact Irritating to eyes. Indication of immediate medical attention and special treatment needed Notes for the doctor Treat symptomatically. 3/11 Revision date: 3/1/2023 Revision: 5 Ceramic Coating 5. Fire-fighting measures Extinguishing media Suitable extinguishing media The product is flammable. Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog. Use fire-extinguishing media suitable for the surrounding fire. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Special hazards arising from the substance or mixture Specific hazards Containers can burst violently or explode when heated, due to excessive pressure build-up. Flammable liquid and vapour. Vapors may be ignited by a spark, a hot surface or an ember. Vapors may form explosive mixtures with air. Fire-water run-off in sewers may create fire or explosion hazard. Hazardous combustion products Thermal decomposition or combustion products may include the following substances: Harmful gases or vapors. Advice for firefighters Protective actions during firefighting Avoid breathing fire gases or vapors. Evacuate area. Keep upwind to avoid inhalation of gases, vapors, fumes and smoke. Ventilate closed spaces before entering them. Cool containers exposed to heat with water spray and remove them from the fire area if it can be done without risk. Cool containers exposed to flames with water until well after the fire is out. If a leak or spill has not ignited, use water spray to disperse vapors and protect men stopping the leak. Control run-off water by containing and keeping it out of sewers and watercourses. If risk of water pollution occurs, notify appropriate authorities. Special protective equipment for firefighters Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing. Standard Firefighter's clothing including helmets, protective boots and gloves will provide a basic level of protection for chemical incidents. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. No action shall be taken without appropriate training or involving any personal risk. Do not touch or walk into spilled material. Evacuate area. Provide adequate ventilation. No smoking, sparks, flames or other sources of ignition near spillage. Promptly remove any clothing that becomes contaminated. Avoid inhalation of vapors and spray/mists. Use suitable respiratory protection if ventilation is inadequate. Environmental precautions Environmental precautions Immiscible with water. Aquatic toxicity is unlikely to occur. However, large or frequent spills may have hazardous effects on the environment. Absorb spillage with non-combustible, absorbent material. Avoid discharge into drains or watercourses or onto the ground. Avoid discharge to the aquatic environment. Methods and material for containment and cleaning up Methods for cleaning up Wear protective clothing as described in Section 8 of this safety data sheet. Clear up spills immediately and dispose of waste safely. Eliminate all ignition sources if safe to do so. No smoking, sparks, flames or other sources of ignition near spillage. Do not allow material to enter confined spaces, due to the risk of explosion. Absorb small quantities with paper towels and evaporate in a safe place. Once evaporation is complete, place paper in a suitable waste disposal container and seal securely. Large Spillages: If the product is soluble in water, dilute the spillage with water and mop it up. Alternatively, or if it is not water- soluble, absorb the spillage with an inert, dry material and place it in a suitable waste disposal container. The contaminated absorbent may pose the same hazard as the spilled material. Label the containers containing waste and contaminated materials and remove from the area as soon as possible. Flush contaminated area with plenty of water. Wash thoroughly after dealing with a spillage. Neutralize with alkali. Caution. May generate heat. Following dilution and neutralization, discharge to the sewer with plenty of water may be permitted. The requirements of the local water authority must be complied with if contaminated water is flushed directly to the sewer. For waste disposal, see Section 13. Reference to other sections For personal protection, see Section 8. See Section 11 for additional information on health hazards. See Section 12 for additional information on ecological hazards. For waste disposal, see Section 13. 7. Handling and storage Precautions for safe handling 4/11 Revision date: 3/1/2023 Revision: 5 Ceramic Coating Usage precautions Read and follow manufacturer's recommendations. Wear protective clothing as described in Section 8 of this safety data sheet. Keep away from food, drink and animal feeding stuffs. Handle all packages and containers carefully to minimize spills. Keep container tightly sealed when not in use. Avoid the formation of mists. The product is flammable. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Suspected of damaging fertility. Suspected of damaging the unborn child. Pregnant or breastfeeding women should not work with this product if there is any risk of exposure. Do not handle until all safety precautions have been read and understood. Do not handle broken packages without protective equipment. Do not reuse empty containers. Advice on general occupational hygiene Wash promptly if skin becomes contaminated. Take off contaminated clothing and wash before reuse. Wash contaminated clothing before reuse. Conditions for safe storage, including any incompatibilities Storage precautions Store away from incompatible materials (see Section 10). Store locked up. Keep away from oxidizing materials, heat and flames. Store away from the following materials: Alkalis. Keep only in the original container. Keep container tightly closed, in a cool, well ventilated place. Keep containers upright. Protect containers from damage. Storage class Flammable liquid storage. Specific end uses(s) Specific end use(s) The identified uses for this product are detailed in Section 1. 8. Exposure controls/Personal protection Control parameters Occupational exposure limits toluene Long-term exposure limit (8-hour TWA): ACGIH 20 ppm A4 Long-term exposure limit (8-hour TWA): OSHA 200 ppm Ceiling exposure limit: OSHA 300 ppm ACGIH = American Conference of Governmental Industrial Hygienists. A4 = Not Classifiable as a Human Carcinogen. OSHA = Occupational Safety and Health Administration. toluene (CAS: 108-88-3) Immediate danger to life and health 500 ppm Exposure controls Protective equipment Appropriate engineering controls Provide adequate ventilation. Eye/face protection Avoid contact with eyes. Large Spillages: Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. Hand protection Wear protective gloves. The most suitable glove should be chosen in consultation with the glove supplier/manufacturer, who can provide information about the breakthrough time of the glove material. To protect hands from chemicals, gloves should comply with OSHA 1910.138 and be demonstrated to be impervious to the chemical and resist degradation. Considering the data specified by the glove manufacturer, check during use that the gloves are retaining their protective properties and change them as soon as any deterioration is detected. Frequent changes are recommended. Other skin and body protection Wear appropriate clothing to prevent any possibility of skin contact. Hygiene measures Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse. 5/11 Revision date: 3/1/2023 Revision: 5 Ceramic Coating Respiratory protection No specific recommendations. Provide adequate ventilation. Large Spillages: If ventilation is inadequate, suitable respiratory protection must be worn. Environmental exposure controls Keep container tightly sealed when not in use. Avoid release to the environment. 9. Physical and chemical properties Information on basic physical and chemical properties Appearance Liquid. Color Clear. Odor Solvent. Odor threshold No information available. pH pH (concentrated solution): 5 Melting point No information available. Initial boiling point and range No information available. Flash point No information available. Evaporation rate No information available. Evaporation factor No information available. Upper/lower flammability or explosive limits No information available. Other flammability No information available. Vapor pressure No information available. Vapor density No information available. Relative density No information available. Bulk density No information available. Solubility(ies) Insoluble in water. Partition coefficient No information available. Auto-ignition temperature No information available. Decomposition Temperature No information available. Viscosity No information available. Explosive properties No information available. Other information None. 10. Stability and reactivity Reactivity See the other subsections of this section for further details. Stability Stable at normal ambient temperatures and when used as recommended. Stable under the prescribed storage conditions. Possibility of hazardous reactions The following materials may react strongly with the product: Oxidizing agents. Conditions to avoid Avoid heat, flames and other sources of ignition. Containers can burst violently or explode when heated, due to excessive pressure build-up. Static electricity and formation of sparks must be prevented. Materials to avoid Alkalis. Amines. Oxidizing materials. Acids - oxidizing. 6/11 Revision date: 3/1/2023 Revision: 5 Ceramic Coating Hazardous decomposition products Does not decompose when used and stored as recommended. Thermal decomposition or combustion products may include the following substances: Harmful gases or vapors. 11. Toxicological information Information on toxicological effects Acute toxicity - oral Summary Based on available data the classification criteria are not met. Acute toxicity - dermal Summary Based on available data the classification criteria are not met. Acute toxicity - inhalation Summary Based on available data the classification criteria are not met. Skin corrosion/irritation Summary Causes skin irritation. Extreme pH Moderate pH ( > 2 and < 11.5). Serious eye damage/irritation Summary Causes serious eye irritation. Respiratory sensitization Summary Based on available data the classification criteria are not met. Skin sensitization Summary Based on available data the classification criteria are not met. Germ cell mutagenicity Summary Based on available data the classification criteria are not met. Carcinogenicity Summary Based on available data the classification criteria are not met. IARC carcinogenicity Contains a substance which may be potentially carcinogenic. IARC Group 3 Not classifiable as to its carcinogenicity to humans. Reproductive toxicity Summary Suspected of damaging fertility. Suspected of damaging the unborn child. Specific target organ toxicity - single exposure Summary May cause respiratory irritation. Target organs Respiratory system, lungs Specific target organ toxicity - repeated exposure Summary Based on available data the classification criteria are not met. Aspiration hazard Summary Based on available data the classification criteria are not met. General information Avoid contact during pregnancy/while nursing. May damage fertility. The severity of the symptoms described will vary dependent on the concentration and the length of exposure. Inhalation A single exposure may cause the following adverse effects: Irritation of nose, throat and airway. Difficulty in breathing. Coughing. Ingestion May cause irritation. Skin Contact Redness. Irritating to skin. Eye contact Irritating to eyes. Route of exposure Ingestion Inhalation Skin and/or eye contact 7/11 Revision date: 3/1/2023 Revision: 5 Ceramic Coating Target Organs Respiratory system, lungs 12. Ecological information Ecotoxicity Not regarded as dangerous for the environment. However, large or frequent spills may have hazardous effects on the environment. Acute aquatic toxicity Summary Based on available data the classification criteria are not met. Chronic aquatic toxicity Summary Based on available data the classification criteria are not met. Persistence and degradability Persistence and degradability The degradability of the product is not known. Bioaccumulative potential Bio-Accumulative Potential No data available on bioaccumulation. Partition coefficient No information available. Mobility in soil Mobility The product is insoluble in water. Volatile liquid. The product contains organic solvents which will evaporate easily from all surfaces. Other adverse effects Other adverse effects None known. 13. Disposal considerations Waste treatment methods General information The generation of waste should be minimized or avoided wherever possible. Reuse or recycle products wherever possible. This material and its container must be disposed of in a safe way. When handling waste, the safety precautions applying to handling of the product should be considered. Care should be taken when handling emptied containers that have not been thoroughly cleaned or rinsed out. Empty containers or liners may retain some product residues and hence be potentially hazardous. Disposal methods Do not empty into drains. Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority. 14. Transport information UN Number UN No. (TDG) 1993 UN No. (IMDG) 1993 UN No. (ICAO) 1993 UN No. (DOT) UN1993 UN proper shipping name Proper shipping name (TDG) FLAMMABLE LIQUID, N.O.S. Proper shipping name (IMDG) FLAMMABLE LIQUID, N.O.S. Proper shipping name (ICAO) FLAMMABLE LIQUID, N.O.S. Proper shipping name (DOT) FLAMMABLE LIQUIDS, N.O.S. Transport hazard class(es) DOT hazard class 3 DOT hazard label 3 8/11 Revision date: 3/1/2023 Revision: 5 Ceramic Coating TDG class 3 TDG label(s) 3 IMDG Class 3 ICAO class/division 3 Transport labels DOT transport labels Packing group TDG Packing Group III IMDG packing group III ICAO packing group III DOT packing group III Environmental hazards Environmentally Hazardous Substance No. Special precautions for user EmS F-E, S-E 15. Regulatory information Regulatory References OSHA Hazard Communication Standard 29 CFR ?1910.1200 US Federal Regulations SARA Section 302 Extremely Hazardous Substances Tier II Threshold Planning Quantities None of the ingredients are listed or exempt. CERCLA/Superfund, Hazardous Substances/Reportable Quantities (EPA) The following ingredients are listed or exempt: toluene Final CERCLA RQ: 1000(454) pounds (Kilograms) SARA Extremely Hazardous Substances EPCRA Reportable Quantities None of the ingredients are listed or exempt. SARA 313 Emission Reporting The following ingredients are listed or exempt: toluene 1.0 % CAA Accidental Release Prevention None of the ingredients are listed or exempt. FDA - Essential Chemical None of the ingredients are listed or exempt. 9/11 Revision date: 3/1/2023 Revision: 5 Ceramic Coating FDA - Precursor Chemical None of the ingredients are listed or exempt. SARA (311/312) Hazard Categories Flammable (gases, aerosols, liquids or solids) Reproductive toxicity Serious eye damage or eye irritation Skin corrosion or irritation Specific target organ toxicity (single or repeated exposure) OSHA Highly Hazardous Chemicals None of the ingredients are listed or exempt. US State Regulations California Proposition 65 Carcinogens and Reproductive Toxins The following ingredients are listed or exempt: Parachlorobenzotrifluoride Carcinogen. toluene Developmental toxin. California Air Toxics "Hot Spots" (A-I) The following ingredients are listed or exempt: toluene California Air Toxics "Hot Spots" (A-II) None of the ingredients are listed or exempt. California Directors List of Hazardous Substances The following ingredients are listed or exempt: toluene Massachusetts "Right To Know" List The following ingredients are listed or exempt: toluene Rhode Island "Right To Know" List The following ingredients are listed or exempt: toluene Minnesota "Right To Know" List The following ingredients are listed or exempt: toluene New Jersey "Right To Know" List The following ingredients are listed or exempt: toluene Pennsylvania "Right To Know" List The following ingredients are listed or exempt: toluene Inventories US - TSCA The following ingredients are listed or exempt: Siloxanes and Silicones 10/11 Revision date: 3/1/2023 Revision: 5 Ceramic Coating Methylcyclopentasiloxane Parachlorobenzotrifluoride toluene US - TSCA 12(b) Export Notification The following ingredients are listed or exempt: Parachlorobenzotrifluoride 16. Other information Abbreviations and acronyms used in the safety data sheet TDG: The transport of dangerous goods act IATA: International air transport association. ICAO: Technical instructions for the safe transport of dangerous goods by air. IMDG: International maritime dangerous goods. CAS: Chemical abstracts service. ATE: Acute toxicity estimate. LC??: Lethal concentration to 50 % of a test population. LD??: Lethal dose to 50% of a test population (median lethal dose). EC??: 50% of maximal effective concentration. PBT: Persistent, bioaccumulative and toxic substance. vPvB: Very persistent and very bioaccumulative. Classification abbreviations and acronyms Flam. Liq. = Flammable liquid Eye Irrit. = Eye irritation Repr. = Reproductive toxicity Skin Irrit. = Skin irritation STOT SE = Specific target organ toxicity-single exposure Training advice Read and follow manufacturer's recommendations. Revision date 3/1/2023 Revision 5 SDS No. 4809 Hazard statements in full H225 Highly flammable liquid and vapor. H226 Flammable liquid and vapor. H227 Combustible liquid. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H361 Suspected of damaging fertility or the unborn child. H361d Suspected of damaging the unborn child. H373 May cause damage to organs through prolonged or repeated exposure. End of safety data sheet. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 11/11 SAFETY DATA SHEET - Ceramic Coating 1. Identification Product identifier Recommended use of the chemical and restrictions on use Details of the supplier of the safety data sheet Emergency telephone number 2. Hazard(s) identification Classification of the substance or mixture Label elements Other hazards 3. Composition/information on ingredients Mixtures 4. First-aid measures Description of first aid measures Most important symptoms and effects, both acute and delayed Indication of immediate medical attention and special treatment needed 5. Fire-fighting measures Extinguishing media Special hazards arising from the substance or mixture Advice for firefighters 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and material for containment and cleaning up 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Specific end uses(s) 8. Exposure controls/Personal protection Control parameters Exposure controls 9. Physical and chemical properties Information on basic physical and chemical properties 10. Stability and reactivity 11. Toxicological information Information on toxicological effects 12. Ecological information Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects 13. Disposal considerations Waste treatment methods 14. Transport information UN Number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Special precautions for user 15. Regulatory information 16. Other information