Revision date: 12/1/2021 Revision: 3 SAFETY DATA SHEET Super Citrus According to Appendix D, OSHA Hazard Communication Standard 29 CFR ?1910.1200 1. Identification Product identifier Product name Super Citrus Product number 1091 Recommended use of the chemical and restrictions on use Application Car maintenance product. Uses advised against No specific uses advised against are identified. Details of the supplier of the safety data sheet Manufacturer 3D International LLC 20724 Centre Pointe Pkwy Unit 1 Santa Clarita, CA 91350 888-999-7627 Emergency telephone number Emergency telephone CHEMTREC 1-800-424-9300 (US and Canada) 2. Hazard(s) identification Classification of the substance or mixture Physical hazards Not Classified Health hazards Skin Irrit. 2 - H315 Eye Dam. 1 - H318 Skin Sens. 1 - H317 Environmental hazards Aquatic Chronic 4 - H413 Label elements Hazard symbols Signal word Danger Hazard statements H315 Causes skin irritation. H318 Causes serious eye damage. H317 May cause an allergic skin reaction. H413 May cause long lasting harmful effects to aquatic life. 1/11 Revision date: 12/1/2021 Revision: 3 Super Citrus Precautionary statements P261 Avoid breathing vapor/ spray. P264 Wash contaminated skin thoroughly after handling. P272 Contaminated work clothing must not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P302+P352 If on skin: Wash with plenty of water. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a poison center/ doctor. P321 Specific treatment (see medical advice on this label). P332+P313 If skin irritation occurs: Get medical advice/ attention. P333+P313 If skin irritation or rash occurs: Get medical advice/ attention. P362+P364 Take off contaminated clothing and wash it before reuse. P501 Dispose of contents/ container in accordance with national regulations. Contains Alcohols, C9-11 ethoxylated, sodium hydroxide, tetrasodium ethylene diamine tetraacetate, (R)-p-mentha- 1,8-diene Other hazards This product does not contain any substances classified as PBT or vPvB. 3. Composition/information on ingredients Mixtures Sodium Xylene Sulfonate 10-30% CAS number: 1300-72-7 Classification Eye Irrit. 2A - H319 Alcohols, C9-11 ethoxylated 10-30% CAS number: 68439-46-3 Classification Acute Tox. 4 - H302 Eye Dam. 1 - H318 sodium hydroxide 1-5% CAS number: 1310-73-2 Classification Met. Corr. 1 - H290 Skin Corr. 1A - H314 Eye Dam. 1 - H318 tetrasodium ethylene diamine tetraacetate 1-5% CAS number: 64-02-8 Classification Acute Tox. 4 - H302 Acute Tox. 4 - H332 Eye Dam. 1 - H318 2/11 Revision date: 12/1/2021 Revision: 3 Super Citrus (R)-p-mentha-1,8-diene <2% CAS number: 5989-27-5 M factor (Acute) = 1 M factor (Chronic) = 1 Classification Flam. Liq. 3 - H226 Skin Irrit. 2 - H315 Skin Sens. 1 - H317 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 The full text for all hazard statements is displayed in Section 16. Composition comments The exact percentage/concentration is withheld as a trade secret in accordance with 29 CFR 1910.1200. 4. First-aid measures Description of first aid measures General information Get medical attention if any discomfort continues. Show this Safety Data Sheet to the medical personnel. Inhalation Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Loosen tight clothing such as collar, tie or belt. Get medical attention if symptoms are severe or persist. Ingestion Rinse mouth thoroughly with water. Get medical advice/attention if you feel unwell. Do not induce vomiting unless under the direction of medical personnel. Skin Contact It is important to remove the substance from the skin immediately. In the event of any sensitization symptoms developing, ensure further exposure is avoided. Remove contamination with soap and water or recognized skin cleansing agent. Get medical attention if symptoms are severe or persist after washing. Eye contact Rinse immediately with plenty of water. Do not rub eye. Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15 minutes and get medical attention. Protection of first aiders First aid personnel should wear appropriate protective equipment during any rescue. Most important symptoms and effects, both acute and delayed General information The severity of the symptoms described will vary dependent on the concentration and the length of exposure. Inhalation A single exposure may cause the following adverse effects: Temporary irritation. Ingestion May cause sensitization or allergic reactions in sensitive individuals. May cause irritation. Skin contact May cause skin sensitization or allergic reactions in sensitive individuals. Redness. Irritating to skin. Eye contact Causes serious eye damage. Symptoms following overexposure may include the following: Pain. Profuse watering of the eyes. Redness. Indication of immediate medical attention and special treatment needed Notes for the doctor Treat symptomatically. May cause sensitization or allergic reactions in sensitive individuals. 5. Fire-fighting measures Extinguishing media Suitable extinguishing media The product is not flammable. Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog. Use fire-extinguishing media suitable for the surrounding fire. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Special hazards arising from the substance or mixture Specific hazards Containers can burst violently or explode when heated, due to excessive pressure build-up. Hazardous combustion products Thermal decomposition or combustion products may include the following substances: Harmful gases or vapors. 3/11 Revision date: 12/1/2021 Revision: 3 Super Citrus Advice for firefighters Protective actions during firefighting Avoid breathing fire gases or vapors. Evacuate area. Cool containers exposed to heat with water spray and remove them from the fire area if it can be done without risk. Cool containers exposed to flames with water until well after the fire is out. If a leak or spill has not ignited, use water spray to disperse vapors and protect men stopping the leak. Avoid discharge to the aquatic environment. Control run-off water by containing and keeping it out of sewers and watercourses. If risk of water pollution occurs, notify appropriate authorities. Special protective equipment for firefighters Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing. Standard Firefighter's clothing including helmets, protective boots and gloves will provide a basic level of protection for chemical incidents. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. No action shall be taken without appropriate training or involving any personal risk. Do not touch or walk into spilled material. Avoid contact with skin and eyes. Environmental precautions Environmental precautions Avoid discharge into drains or watercourses or onto the ground. Avoid discharge to the aquatic environment. Methods and material for containment and cleaning up Methods for cleaning up Wear protective clothing as described in Section 8 of this safety data sheet. Clear up spills immediately and dispose of waste safely. If the product is soluble in water, dilute the spillage with water and mop it up. Alternatively, or if it is not water-soluble, absorb the spillage with an inert, dry material and place it in a suitable waste disposal container. The contaminated absorbent may pose the same hazard as the spilled material. Label the containers containing waste and contaminated materials and remove from the area as soon as possible. Flush contaminated area with plenty of water. Wash thoroughly after dealing with a spillage. Neutralize with acid. Caution. May generate heat. Dangerous for the environment. Do not empty into drains. For waste disposal, see Section 13. Reference to other sections For personal protection, see Section 8. See Section 11 for additional information on health hazards. See Section 12 for additional information on ecological hazards. For waste disposal, see Section 13. 7. Handling and storage Precautions for safe handling Usage precautions Read and follow manufacturer's recommendations. Wear protective clothing as described in Section 8 of this safety data sheet. Keep away from food, drink and animal feeding stuffs. Handle all packages and containers carefully to minimize spills. Keep container tightly sealed when not in use. Avoid the formation of mists. Avoid discharge to the aquatic environment. Do not handle until all safety precautions have been read and understood. Do not handle broken packages without protective equipment. Do not reuse empty containers. Advice on general occupational hygiene Wash promptly if skin becomes contaminated. Take off contaminated clothing and wash before reuse. Wash contaminated clothing before reuse. Conditions for safe storage, including any incompatibilities Storage precautions Store away from incompatible materials (see Section 10). Keep out of the reach of children. Keep away from food, drink and animal feeding stuffs. Store away from the following materials: Acids. Keep only in the original container. Keep container tightly closed, in a cool, well ventilated place. Keep containers upright. Protect containers from damage. Storage class Acid-reactive storage. Specific end uses(s) Specific end use(s) The identified uses for this product are detailed in Section 1. 8. Exposure controls/Personal protection Control parameters 4/11 Revision date: 12/1/2021 Revision: 3 Super Citrus Occupational exposure limits sodium hydroxide Ceiling exposure limit: ACGIH 2 mg/m? Long-term exposure limit (8-hour TWA): OSHA 2 mg/m? ACGIH = American Conference of Governmental Industrial Hygienists. OSHA = Occupational Safety and Health Administration. sodium hydroxide (CAS: 1310-73-2) Immediate danger to life and health 10 mg/m? Exposure controls Protective equipment Appropriate engineering controls Provide adequate ventilation. Eye/face protection Avoid contact with eyes. Large Spillages: Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. Hand protection Wear protective gloves. The most suitable glove should be chosen in consultation with the glove supplier/manufacturer, who can provide information about the breakthrough time of the glove material. To protect hands from chemicals, gloves should comply with OSHA 1910.138 and be demonstrated to be impervious to the chemical and resist degradation. Considering the data specified by the glove manufacturer, check during use that the gloves are retaining their protective properties and change them as soon as any deterioration is detected. Frequent changes are recommended. Other skin and body protection May cause skin sensitization or allergic reactions in sensitive individuals. Wear appropriate clothing to prevent repeated or prolonged skin contact. Hygiene measures Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse. Respiratory protection No specific recommendations. Provide adequate ventilation. Large Spillages: If ventilation is inadequate, suitable respiratory protection must be worn. Environmental exposure controls Keep container tightly sealed when not in use. Avoid release to the environment. 9. Physical and chemical properties Information on basic physical and chemical properties Appearance Liquid. Color Yellow. Odor Citrus. Odor threshold No information available. pH pH (concentrated solution): 12 Melting point No information available. Initial boiling point and range No information available. Flash point No information available. Evaporation rate No information available. Evaporation factor No information available. Upper/lower flammability or explosive limits No information available. 5/11 Revision date: 12/1/2021 Revision: 3 Super Citrus Vapor pressure No information available. Vapor density No information available. Relative density ~ 1.19 Bulk density No information available. Solubility(ies) Soluble in water. Partition coefficient No information available. Auto-ignition temperature No information available. Decomposition Temperature No information available. Viscosity No information available. Explosive properties No information available. Other information None. 10. Stability and reactivity Reactivity See the other subsections of this section for further details. Stability Stable at normal ambient temperatures and when used as recommended. Stable under the prescribed storage conditions. Possibility of hazardous reactions No potentially hazardous reactions known. Conditions to avoid There are no known conditions that are likely to result in a hazardous situation. Materials to avoid Acid anhydrides. Acids. Phenols, cresols. Hazardous decomposition products Does not decompose when used and stored as recommended. Thermal decomposition or combustion products may include the following substances: Harmful gases or vapors. 11. Toxicological information Information on toxicological effects Acute toxicity - oral Summary Based on available data the classification criteria are not met. ATE oral (mg/kg) 2,541.94 Acute toxicity - dermal Summary Based on available data the classification criteria are not met. Acute toxicity - inhalation Summary Based on available data the classification criteria are not met. ATE inhalation (dusts/mists mg/l) 32.33 Skin corrosion/irritation Summary Causes skin irritation. Extreme pH ? 11.5 Corrosive. Serious eye damage/irritation Summary Causes serious eye damage. Respiratory sensitization Summary Based on available data the classification criteria are not met. Skin sensitization 6/11 Revision date: 12/1/2021 Revision: 3 Super Citrus Summary May cause an allergic skin reaction. Germ cell mutagenicity Summary Based on available data the classification criteria are not met. Carcinogenicity Summary Based on available data the classification criteria are not met. IARC carcinogenicity Contains a substance which may be potentially carcinogenic. IARC Group 3 Not classifiable as to its carcinogenicity to humans. Reproductive toxicity Summary Based on available data the classification criteria are not met. Specific target organ toxicity - single exposure Summary Based on available data the classification criteria are not met. Specific target organ toxicity - repeated exposure Summary Based on available data the classification criteria are not met. Aspiration hazard Summary Based on available data the classification criteria are not met. General information The severity of the symptoms described will vary dependent on the concentration and the length of exposure. Inhalation A single exposure may cause the following adverse effects: Temporary irritation. Ingestion May cause sensitization or allergic reactions in sensitive individuals. May cause irritation. Skin Contact May cause skin sensitization or allergic reactions in sensitive individuals. Redness. Irritating to skin. Eye contact Causes serious eye damage. Symptoms following overexposure may include the following: Pain. Profuse watering of the eyes. Redness. Route of exposure Ingestion Inhalation Skin and/or eye contact Target Organs No specific target organs known. Medical considerations Skin disorders and allergies. 12. Ecological information Acute aquatic toxicity Summary Based on available data the classification criteria are not met. Chronic aquatic toxicity Summary May cause long lasting harmful effects to aquatic life. Persistence and degradability Persistence and degradability The degradability of the product is not known. Bioaccumulative potential Bio-Accumulative Potential No data available on bioaccumulation. Partition coefficient No information available. Mobility in soil Mobility The product is water-soluble and may spread in water systems. Other adverse effects Other adverse effects None known. 13. Disposal considerations 7/11 Revision date: 12/1/2021 Revision: 3 Super Citrus Waste treatment methods General information The generation of waste should be minimized or avoided wherever possible. Reuse or recycle products wherever possible. This material and its container must be disposed of in a safe way. When handling waste, the safety precautions applying to handling of the product should be considered. Care should be taken when handling emptied containers that have not been thoroughly cleaned or rinsed out. Empty containers or liners may retain some product residues and hence be potentially hazardous. Disposal methods Do not empty into drains. Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority. 14. Transport information General For limited quantity packaging/limited load information, consult the relevant modal documentation using the data shown in this section. UN Number UN No. (TDG) 1760 UN No. (IMDG) 1760 UN No. (ICAO) 1760 UN No. (DOT) UN1760 UN proper shipping name Proper shipping name (TDG) CORROSIVE LIQUID, N.O.S. Proper shipping name (IMDG) CORROSIVE LIQUID, N.O.S. Proper shipping name (ICAO) CORROSIVE LIQUID, N.O.S. Proper shipping name (DOT) CORROSIVE LIQUIDS, N.O.S. Transport hazard class(es) DOT hazard class 8 DOT hazard label 8 TDG class 8 TDG label(s) 8 IMDG Class 8 ICAO class/division 8 Transport labels DOT transport labels Packing group TDG Packing Group II IMDG packing group II ICAO packing group II DOT packing group II Environmental hazards 8/11 Revision date: 12/1/2021 Revision: 3 Super Citrus Environmentally Hazardous Substance No. Special precautions for user Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. EmS F-A, S-B 15. Regulatory information Regulatory References OSHA Hazard Communication Standard 29 CFR ?1910.1200 US Federal Regulations SARA Section 302 Extremely Hazardous Substances Tier II Threshold Planning Quantities None of the ingredients are listed or exempt. CERCLA/Superfund, Hazardous Substances/Reportable Quantities (EPA) The following ingredients are listed or exempt: sodium hydroxide Final CERCLA RQ: 1000(454) pounds (Kilograms) SARA Extremely Hazardous Substances EPCRA Reportable Quantities None of the ingredients are listed or exempt. SARA 313 Emission Reporting The following ingredients are listed or exempt: Sodium Xylene Sulfonate 0.1 % tetrasodium ethylene diamine tetraacetate 0.1 % CAA Accidental Release Prevention None of the ingredients are listed or exempt. FDA - Essential Chemical None of the ingredients are listed or exempt. FDA - Precursor Chemical None of the ingredients are listed or exempt. SARA (311/312) Hazard Categories Respiratory or skin sensitization Serious eye damage or eye irritation Skin corrosion or irritation OSHA Highly Hazardous Chemicals None of the ingredients are listed or exempt. US State Regulations California Proposition 65 Carcinogens and Reproductive Toxins None of the ingredients are listed or exempt. California Air Toxics "Hot Spots" (A-I) The following ingredients are listed or exempt: sodium hydroxide California Air Toxics "Hot Spots" (A-II) None of the ingredients are listed or exempt. 9/11 Revision date: 12/1/2021 Revision: 3 Super Citrus California Directors List of Hazardous Substances The following ingredients are listed or exempt: sodium hydroxide Massachusetts "Right To Know" List The following ingredients are listed or exempt: sodium hydroxide Rhode Island "Right To Know" List The following ingredients are listed or exempt: sodium hydroxide Minnesota "Right To Know" List The following ingredients are listed or exempt: sodium hydroxide New Jersey "Right To Know" List The following ingredients are listed or exempt: sodium hydroxide Pennsylvania "Right To Know" List The following ingredients are listed or exempt: sodium hydroxide Inventories US - TSCA All the ingredients are listed or exempt. US - TSCA 12(b) Export Notification None of the ingredients are listed or exempt. 16. Other information Abbreviations and acronyms used in the safety data sheet TDG: The transport of dangerous goods act IATA: International air transport association. ICAO: Technical instructions for the safe transport of dangerous goods by air. IMDG: International maritime dangerous goods. CAS: Chemical abstracts service. ATE: Acute toxicity estimate. LC??: Lethal concentration to 50 % of a test population. LD??: Lethal dose to 50% of a test population (median lethal dose). EC??: 50% of maximal effective concentration. PBT: Persistent, bioaccumulative and toxic substance. vPvB: Very persistent and very bioaccumulative. Classification abbreviations and acronyms Eye Dam. = Serious eye damage Skin Irrit. = Skin irritation Skin Sens. = Skin sensitisation Aquatic Chronic = Hazardous to the aquatic environment (chronic) Training advice Read and follow manufacturer's recommendations. Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision. Revision date 12/1/2021 Revision 3 10/11 Revision date: 12/1/2021 Revision: 3 Super Citrus SDS No. 4707 Hazard statements in full H226 Flammable liquid and vapor. H290 May be corrosive to metals. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H413 May cause long lasting harmful effects to aquatic life. End of safety data sheet. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 11/11 SAFETY DATA SHEET - Super Citrus 1. Identification Product identifier Recommended use of the chemical and restrictions on use Details of the supplier of the safety data sheet Emergency telephone number 2. Hazard(s) identification Classification of the substance or mixture Label elements Other hazards 3. Composition/information on ingredients Mixtures 4. First-aid measures Description of first aid measures Most important symptoms and effects, both acute and delayed Indication of immediate medical attention and special treatment needed 5. Fire-fighting measures Extinguishing media Special hazards arising from the substance or mixture Advice for firefighters 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and material for containment and cleaning up 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Specific end uses(s) 8. Exposure controls/Personal protection Control parameters Exposure controls 9. Physical and chemical properties Information on basic physical and chemical properties 10. Stability and reactivity 11. Toxicological information Information on toxicological effects 12. Ecological information Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects 13. Disposal considerations Waste treatment methods 14. Transport information UN Number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Special precautions for user 15. Regulatory information 16. Other information