PTU Synthetic Lubricant 2 Safety Data Sheet Product name PTU Synthetic Lubricant 2 : 1.1 Product identifier 1.3 Details of the supplier of the safety data sheet Liquid.Product type : e-mail address of person responsible for this SDS : 1.2 Relevant identified uses of the substance or mixture and uses advised against SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.4 Emergency telephone number Telephone number : Hours of operation : Afton Chemical Limited Euro-Tech Centre London Road, Bracknell, RG12 2UW, England Tel: +44 1344 304141 PTU Synthetic LubricantSDS no. Petrochemical industry: Lubricants Gear oils Lubricant and Fuel additives: This email address is being protected from spambots. You need JavaScript enabled to view it. Metalworking Fluids: This email address is being protected from spambots. You need JavaScript enabled to view it. Afton Chemical Limited Ashburton Road West, Trafford Park, Manchester, M17 1SX, England Tel: +44 161 876 5673 Afton Chemical SPRL (Feluy Plant) Rue de Scouffl?ny, 50 B-7191 Ecaussinnes Lalaing, Belgium Tel: +32 67 286211 +43-13649237 (Austria) +32-28083237 (Belgium) +359-32570104 (Bulgaria) +385-17776920 (Croatia) +420-228880039 (Czech Republic) +45-69918573 (Denmark) +358-942419014 (Finland) +33-975181407 (France) +36-18088425 (Hungary) +353-19014670 (Ireland) +39-0245557031 (Italy) +352-20202416 (Luxembourg) +31-858880596 (The Netherlands) +47-21930678 (Norway) +48-223988029 (Poland) +351-308801773 (Portugal) +421-233057972 (Slovakia) +38-618888016 (Slovenia) +46-852503403 (Swedish) +41-435082011 (Switzerland) +380-947101374 (Ukraine) +44-8708200418 (UK) 24 hours a day, 7 days a week +1-703-527-3887 (International) +65-3158-1349 (Asia Pacific) +61-290372994 (Australia) 4001-204937 (China) 000-800-100-7141 (India) +81-345209637 (Japan) 00-308-13-2549 (South Korea) +1-703-741-5979 (Spanish language) 1-800-424-9300 (US & Canada) See section 7.3 and where applicable the annex to this Safety Data Sheet for further information on the relevant uses. Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS] SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Product definition : Mixture Classification according to Directive 1999/45/EC [DPD] Aquatic Chronic 3, H412 The product is classified as hazardous according to Regulation (EC) 1272/2008 as amended. The product is classified as dangerous according to Directive 1999/45/EC and its amendments. Classification R52/53: :Environmental hazards Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Date:14 February 2017 Version : 2.01 1/12PTU Synthetic Lubricant 2 10-4105,19351882 ACDelco PTU Synthetic Lubricant MZ7G2L Stamp Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 SECTION 2: Hazards identification :Other hazards which do not result in classification None known. See Section 11 for more detailed information on health effects and symptoms. See Section 12 for environmental precautions. See Section 16 for the full text of the R phrases or H statements declared above. 2.2 Label elements Signal word : Hazard statements : Prevention : Precautionary statements Response : Storage : Disposal : No signal word. Harmful to aquatic life with long lasting effects. Avoid release to the environment. Not applicable. Store in a well-ventilated place. Dispose of contents and container in accordance with all local, regional, national and international regulations. Supplemental label elements : Contains Long-chain alkyl amine and Alkyl polysulfides. May produce an allergic reaction. 2.3 Other hazards Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles : Not applicable. SECTION 3: Composition/information on ingredients Product / ingredient name Mineral oil Mixture 1 - 4.9 Not classified. Not classified. [2] Methacrylate copolymer Proprietary 1 - 4.9 Xi; R36 Eye Irrit. 2, H319 [1] Alkyl polysulfides EC: 273-103-3 0.5 - 0.99 Xi; R38 Skin Sens. 1B, H317 [1] CAS: 68937-96-2 R43 Aquatic Acute 1, H400 N; R50/53 Aquatic Chronic 1, H410 Long-chain alkyl amine REACH #: 01-2119456798-18 0.1 - 0.5 T; R23/24 Acute Tox. 4, H302 [1] EC: 273-279-1 Xn; R22 Acute Tox. 3, H311 CAS: 68955-53-3 C; R34 Acute Tox. 2, H330 R43 Skin Corr. 1B, H314 N; R50/53 Skin Sens. 1A, H317 STOT SE 3, H335 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Long-chain alkyl amine with substituted heteromonocyclic Proprietary 0.1 - 0.5 Xn; R20 Acute Tox. 4, H332 [1] Xi; R41, R38 Skin Irrit. 2, H315 N; R50/53 Eye Dam. 1, H318 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Long-chain alkenyl amine EC: 204-015-5 0.1 - 0.5 Xn; R22, R48/22, R65 Acute Tox. 4, H302 [1] CAS: 112-90-3 C; R34 Skin Corr. 1B, H314 N; R50/53 Eye Dam. 1, H318 STOT SE 3, H335 STOT RE 2, H373 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Identifiers 67/548/EEC There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment, are PBTs or vPvBs or have been assigned a workplace exposure limit and hence require reporting in this section. % TypeRegulation (EC) No. 1272/2008 [CLP] Classification : Mixture See Section 16 for the full text of the R phrases or H statements declared above. Product definition Date:14 February 2017 Version : 2.01 2/12PTU Synthetic Lubricant 2 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 SECTION 3: Composition/information on ingredients [1] Substance classified with a health or environmental hazard [2] Substance with a workplace exposure limit [3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII [4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII [5] Substance of equivalent concern If REACH registration numbers do not appear the substance is either exempt from registration, does not meet the minimum volume threshold for registration, the registration date has not yet come due or this information is proprietary. The mineral oils in the product contain < 3% DMSO extract (IP 346). Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Skin contact Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if irritation occurs. Wash clothing before reuse. Clean shoes thoroughly before reuse. 4.1 Description of first aid measures If inhaled, remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. If not breathing, give artificial respiration. If breathing is difficult, administer oxygen. Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Ingestion Inhalation Eye contact : : : : : Specific treatments Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. SECTION 4: First aid measures 4.2 Most important symptoms and effects, both acute and delayed Potential acute health effects Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards.:Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation No specific data.: : : Eye contact : No specific data. 4.3 Indication of any immediate medical attention and special treatment needed No specific treatment.: No specific data. No specific data. Hazards from the substance or mixture In a fire or if heated, a pressure increase will occur and the container may burst. This material is harmful to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. In case of fire, use water spray (fog), foam, dry chemical or CO2. 5.1 Extinguishing media : Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : SECTION 5: Firefighting measures 5.2 Special hazards arising from the substance or mixture Date:14 February 2017 Version : 2.01 3/12PTU Synthetic Lubricant 2 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 SECTION 5: Firefighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products Decomposition products may include the following materials: carbon dioxide carbon monoxide Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire- fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents. Special protective equipment for fire-fighters : : 5.3 Advice for firefighters Special protective actions for fire-fighters : Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Large spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water- soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : 6.3 Methods and materials for containment and cleaning up SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures For non-emergency personnel : For emergency responders : 6.4 Reference to other sections See Section 1 for emergency contact information. See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste treatment information. No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". : 6.2 Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. : SECTION 7: Handling and storage The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). 7.1 Precautions for safe handling Date:14 February 2017 Version : 2.01 4/12PTU Synthetic Lubricant 2 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 SECTION 7: Handling and storage Protective measures : Advice on general occupational hygiene : 7.3 Specific end use(s) Recommendations : :Industrial sector specific solutions Not available. Not available. Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Avoid release to the environment. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. 7.2 Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well- ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Occupational exposure limits SECTION 8: Exposure controls/personal protection 8.1 Control parameters Product / ingredient name Exposure limit values Mineral oil EH40-MEL (Europe, 2002). TWA: 5 mg/m? 8 hours. Mineral oil Arbejdstilsynet (Denmark). GV: 1 mg/m? Europe Denmark Mineral oil Lijst Grenswaarden / Valeurs Limites (Belgium). TWA: 5 mg/m? 8 hours. STEL: 10 mg/m? 15 minutes. Belgium Mineral oil Ty?terveyslaitos, Sosiaali- ja terveysministeri? (Finland). TWA: 5 mg/m? 8 hours. Finland Czech Republic Mineral oil 178/2001 (Czech Republic). TWA: 5 mg/m? 8 hours. CEIL: 10 mg/m? Mineral oil Ministero della Salute (Italy). TWA: 5 mg/m? 8 hours. Italy Mineral oil NAOSH (Ireland). OELV: 5 mg/m? 8 hours. Ireland Hungary Mineral oil E?M-SzCsM (Hungary). CEIL: 5 mg/m? Latvia Greece Mineral oil PD 90/1999 (Greece). TWA: 5 mg/m? 8 hours. Mineral oil ?? ???? ? ?? ??????? ?13/2003 (Bulgaria). Limit value 8 hours: 5 mg/m? Bulgaria The information in this section contains generic advice and guidance. Information is provided based on typical anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could significantly increase worker exposure or environmental releases. Date:14 February 2017 Version : 2.01 5/12PTU Synthetic Lubricant 2 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 SECTION 8: Exposure controls/personal protection Recommended monitoring procedures If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required. : Appropriate engineering controls : Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. 8.2 Exposure controls Hygiene measures : No DNELs/DMELs available. Predicted No Effect Concentration No PNECs available. Derived No Effect Level Individual protection measures Mineral oil AFS 2005:17 (Sweden). NGV: 1 mg/m? KTV: 3 mg/m? Mineral oil Arbeidstilsynet (Norway). AN: 1 mg/m? Mineral oil Nationale MAC-lijst (Netherlands). TGG: 5 mg/m? 8 hours. Sweden Norway Netherlands Spain Mineral oil INSHT (Spain). VLA-ED: 5 mg/m? 8 hours. VLA-EC: 10 mg/m? 15 minutes. Lithuania Slovakia Mineral oil Del Lietuvos Higienos Normos (Lithuania). TWA: 1 mg/m? 8 hours. STEL: 3 mg/m? 15 minutes. Mineral oil Nariadenie Vl?dy Slovenskej republiky (Slovakia). TWA: 5 mg/m? 8 hours. Poland Mineral oil Rozporz?dzenie Ministra Pracy i Polityki Spo?ecznej (Poland). TWA: 5 mg/m? 8 hours. STEL: 10 mg/m? 15 minutes. Mineral oil LV Nat. Standardisation and Meterological Centre (Latvia). TWA: 5 mg/m? 8 hours. Portugal Mineral oil Instituto Portugu?s da Qualidade (Portugal). TLV-TWA: 5 mg/m? 8 hours. STEL: 10 mg/m? Mineral oil Ministerul Muncii, Solidarit??ii Sociale ?i Familiei, ?i Ministerul S?n?t??ii Publice (Romania). VLA: 5 mg/m? 8 hours. Termen scurt: 10 mg/m? 15 minutes. Romania Derived No Effect Level / Predicted No Effect Concentration If DNEL's or PNEC's are shown, these are for the potential Risk Determining Substances for the product. The specific Risk Determining Substances for the product are listed in the exposure scenarios found in the annex to this Safety Data Sheet. Date:14 February 2017 Version : 2.01 6/12PTU Synthetic Lubricant 2 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 SECTION 8: Exposure controls/personal protection Hand protection Use appropriate respiratory protection if there is the potential to exceed the exposure limit(s). Seek professional advice prior to respirator selection and use. Select respirator based on suitability to provide adequate worker protection for given working conditions and level of airborne contaminant. Hand Protection: Wear chemical resistant gloves. Nitrile gloves of minimum thickness 0.4 mm have an expected breakthrough time of 480 minutes or less when in frequent contact with the product. Due to variable exposure conditions the user must consider that the practical use of a chemical-protective glove in practice may be much shorter than the permeation time above. Manufacturer?s directions for use, especially about the minimum thickness and the minimum breakthrough time, must be observed. This information does not replace suitability tests by the end user since glove protection varies depending on the conditions under which the product is used. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields. Eye/face protection Respiratory protection : : : Skin protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Body protection : Not available. Physical state Melting point/freezing point Initial boiling point and boiling range Vapor pressure Relative density Vapor density Solubility(ies) Liquid. Not available. 0.853 Not available. Not available. Not available. Not available.Odor pH Not available.Color Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Closed cup: 182?C [Minimum Pensky-Martens.] Not available. Not available. Not available. Not available. Viscosity Kinematic (40?C): 0.8575 cm2/s Not available.Odor threshold Partition coefficient: n-octanol/ water Upper/lower flammability or explosive limits Explosive properties : : : : : : : : : : : : : : : : : : Not available.Oxidizing properties : 9.1 Information on basic physical and chemical properties Appearance 9.2 Other information Decomposition temperature : Not available. SECTION 9: Physical and chemical properties Flammability (solid, gas) : No additional information. Density : 0.88 g/cm? [15.6?C] 15.2 cSt @ 100?C Not applicable. (liquid). Date:14 February 2017 Version : 2.01 7/12PTU Synthetic Lubricant 2 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 10.6 Hazardous decomposition products 10.4 Conditions to avoid High temperatures, sparks, and open flames. Decomposition products may include the following materials: carbon dioxide carbon monoxide Under recommended handling and storage conditions the product is stable.10.2 Chemical stability Strong oxidizing and reducing agents. : : : 10.5 Incompatible materials : 10.3 Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. SECTION 10: Stability and reactivity 10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients. Acute toxicity Mineral oil LC50 Inhalation Vapor Rat >5000 mg/m? 4 hours LD50 Dermal Rabbit >5000 mg/kg - LD50 Oral Rat >5000 mg/kg - Alkyl polysulfides LD50 Dermal Rabbit >2000 mg/kg - LD50 Oral Rat 2551 mg/kg - LD50 Oral Rat 6500 mg/kg - Long-chain alkyl amine LC50 Inhalation Vapor Rat - Female 1.19 mg/l 4 hours LD50 Dermal Rat 251 mg/kg - LD50 Oral Rat 612 mg/kg - Long-chain alkyl amine with substituted heteromonocyclic LD50 Dermal Rabbit >2000 mg/kg - LD50 Oral Rat >2000 mg/kg - Long-chain alkenyl amine LD50 Oral Rat 1689 mg/kg - Product / ingredient name Result Species Dose Exposure Conclusion/Summary : Based on available data, the classification criteria are not met. Carcinogenicity Conclusion/Summary : Based on available data, the classification criteria are not met. Mutagenicity Conclusion/Summary : Based on available data, the classification criteria are not met. Teratogenicity Conclusion/Summary : Based on available data, the classification criteria are not met. Reproductive toxicity Conclusion/Summary : Based on available data, the classification criteria are not met. Irritation/Corrosion Conclusion/Summary Skin : Based on available data, the classification criteria are not met. Eyes : Based on available data, the classification criteria are not met. Respiratory : Based on available data, the classification criteria are not met. Sensitization Conclusion/Summary Skin : Not classified as a skin sensitizer. Based on test data of the skin sensitizing ingredient/s at similar or higher concentrations than are present in this product. Respiratory : Based on available data, the classification criteria are not met. SECTION 11: Toxicological information 11.1 Information on toxicological effects Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Product / ingredient name Category Product / ingredient name Category Route of exposure Target organs Route of exposure Target organs Long-chain alkyl amine Category 3 Not applicable. Respiratory tract irritation Long-chain alkenyl amine Category 3 Not applicable. Respiratory tract irritation Long-chain alkenyl amine Category 2 Not determined Not determined Date:14 February 2017 Version : 2.01 8/12PTU Synthetic Lubricant 2 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 SECTION 11: Toxicological information Potential chronic health effects Potential acute health effects Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards.:Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards.:Eye contact No known significant effects or critical hazards.General : No known significant effects or critical hazards.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Based on available data, the classification criteria are not met. Conclusion/Summary : Based on available data, the classification criteria are not met. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : No specific data. Not available. Aspiration hazard Product / ingredient name Result Information on the likely routes of exposure : Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Long term exposure Potential immediate effects Potential delayed effects : : Potential immediate effects Potential delayed effects : : Other information : Not available. Not available. Long-chain alkenyl amine ASPIRATION HAZARD - Category 1 Not available. Inhalation of oil mist or vapors at elevated temperatures may cause respiratory irritation. Ingestion may cause gastrointestinal irritation and diarrhea. Repeated or prolonged contact with the mixture may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Mobility Not available.: 12.3 Bioaccumulative potential Based on available data, the classification criteria are not met. 12.1 Toxicity Long-chain alkenyl amine EC50 0.03 mg/l Algae 96 hours EC50 0.011 mg/l Daphnia 48 hours LC50 0.11 mg/l Fish 96 hours Product / ingredient name SpeciesResult Exposure Conclusion/Summary : Harmful to aquatic life with long lasting effects. 12.2 Persistence and degradability Conclusion/Summary : Based on available data, the classification criteria are not met. PBT : Not applicable. vPvB : Not applicable. SECTION 12: Ecological information 12.4 Mobility in soil Soil/water partition coefficient (KOC) Not available.: 12.5 Results of PBT and vPvB assessment Date:14 February 2017 Version : 2.01 9/12PTU Synthetic Lubricant 2 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 SECTION 12: Ecological information 12.6 Other adverse effects No known significant effects or critical hazards.: :Methods of disposal SECTION 13: Disposal considerations The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). 13.1 Waste treatment methods Product Special precautions : This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. SECTION 14: Transport information 14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code : Not available. - - - - - - - - - Not regulated.Not regulated. Not regulated. - - - ADR/RID IMDG IATA 14.1 UN number 14.2 UN proper shipping name 14.3 Transport hazard class(es) 14.4 Packing group ADN Additional information 14.5 Environmental hazards 14.6 Special precautions for user No. No. No. Not regulated. - - - : - No. Transport within user?s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Europe : At least one component is not listed. SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Canada : At least one component is not listed. Japan : New Zealand : At least one component is not listed. Australia : At least one component is not listed. China : At least one component is not listed. Republic of Korea : At least one component is not listed. Philippines : At least one component is not listed. Taiwan. : All components are listed or exempted. United States : All components are listed or exempted. Other EU regulations International Inventory Status At least one component is not listed. Date:14 February 2017 Version : 2.01 10/12PTU Synthetic Lubricant 2 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 SECTION 15: Regulatory information 3 Appendix No. 4Hazard class for water : Sweden Germany 15.2 Chemical Safety Assessment This product contains substances for which Chemical Safety Assessments are still required.: Product registration number : Not applicable. When included, the exposure scenarios were determined based on a review of the risk determining substances and the intended product application. Safe use is demonstrated through using the ATC, ATIEL and Afton systems for Generic Exposure Scenarios for mixtures. Further information on these systems is available by contacting Afton at the email address in section 1. Indicates information that has changed from previously issued version. SECTION 16: Other information Abbreviations and acronyms : ATE = Acute Toxicity Estimate CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008] DMEL = Derived Minimal Effect Level DNEL = Derived No Effect Level EUH statement = CLP-specific Hazard statement PBT = Persistent, Bioaccumulative and Toxic PNEC = Predicted No Effect Concentration RRN = REACH Registration Number vPvB = Very Persistent and Very Bioaccumulative Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS] Classification Justification Aquatic Chronic 3, H412 Expert judgment Europe Full text of abbreviated H statements : Full text of classifications [CLP/GHS] : H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H330 Fatal if inhaled. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. Acute Tox. 2, H330 ACUTE TOXICITY (inhalation) - Category 2 Acute Tox. 3, H311 ACUTE TOXICITY (dermal) - Category 3 Acute Tox. 4, H302 ACUTE TOXICITY (oral) - Category 4 Aquatic Acute 1, H400 AQUATIC HAZARD (ACUTE) - Category 1 Aquatic Chronic 1, H410 AQUATIC HAZARD (LONG-TERM) - Category 1 Aquatic Chronic 3, H412 AQUATIC HAZARD (LONG-TERM) - Category 3 Asp. Tox. 1, H304 ASPIRATION HAZARD - Category 1 Eye Dam. 1, H318 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 Eye Irrit. 2, H319 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2 Skin Corr. 1B, H314 SKIN CORROSION/IRRITATION - Category 1B Skin Irrit. 2, H315 SKIN CORROSION/IRRITATION - Category 2 Skin Sens. 1A, H317 SKIN SENSITIZATION - Category 1A Skin Sens. 1B, H317 SKIN SENSITIZATION - Category 1B STOT RE 2, H373 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 STOT SE 3, H335 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Date:14 February 2017 Version : 2.01 11/12PTU Synthetic Lubricant 2 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 SECTION 16: Other information Date of issue/ Date of revision This information and these recommendations are offered in good faith and believed to be correct as of the date hereof. Information and recommendations are supplied upon the condition that the recipients will make their own decision as to safety and suitability for their purposes. No representations or warranties, either expressed or implied, of merchantability, fitness for a particular purpose, or of any other nature, are made with respect to the product or the information and recommendations. Afton makes no representation as to completeness or accuracy. In no event will Afton be responsible for damages of any nature whatsoever resulting from the use or reliance upon the information and recommendations. Notice to reader Date of previous issue : : 14 February 2017 2.00 R23/24- Toxic by inhalation and in contact with skin. R22- Harmful if swallowed. R48/22- Harmful: danger of serious damage to health by prolonged exposure if swallowed. R65- Harmful: may cause lung damage if swallowed. R34- Causes burns. R41- Risk of serious damage to eyes. R36- Irritating to eyes. R38- Irritating to skin. R43- May cause sensitization by skin contact. R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Full text of abbreviated R phrases : T - Toxic C - Corrosive Xn - Harmful Xi - Irritant N - Dangerous for the environment :Full text of classifications [DSD/DPD] Date:14 February 2017 Version : 2.01 12/12PTU Synthetic Lubricant 2