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LPS? Cold Galvanize ITW Pro Brands. -GA Part Number: 00516 Version No: 1.5 Safety Data Sheet according to OSHA HazCom Standard (2012) requirements Issue Date: 01/05/2024 Print Date: 06/05/2024 S.GHS.USA.EN SECTION 1 Identification Product Identifier Product name LPS? Cold Galvanize Proper shipping name Aerosols, flammable, (each not exceeding 1 L capacity) Other means of identification Not Available Recommended use of the chemical and restrictions on use Relevant identified uses For Industrial Use OnlyUse according to manufacturer's directions. Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party Registered company name ITW Pro Brands. -GA Address 4647 Hugh Howell Rd. Tucker, GA United States Telephone 770-243-8800 Fax Not Available Website Email This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency phone number Association / Organisation Dykem/Dymon/Scrubs = Call InfoTrac For_LPS & Other Brands = Call Chemtrec Emergency telephone numbers 1-800-535-5053 (InfoTrac Inside US) 1-800-424-9300 (Chemtrec Inside US) Other emergency telephone numbers 1-352-323-3500 (Infotrac Ouside US) +001 703-527-3887 (Chemtrec Outside US) SECTION 2 Hazard(s) identification Classification of the substance or mixture Classification Aerosols Category 1, Gases Under Pressure (Liquefied Gas), Skin Corrosion/Irritation Category 2, Specific Target Organ Toxicity - SingleExposure (Narcotic Effects) Category 3, Reproductive Toxicity Category 1B, Specific Target Organ Toxicity - Repeated Exposure Category 2 Label elements Hazard pictogram(s) Signal word Danger Hazard statement(s) H222 Extremely flammable aerosol. H280 Contains gas under pressure; may explode if heated. H315 Causes skin irritation. H336 May cause drowsiness or dizziness. H360 May damage fertility or the unborn child. H373 May cause damage to organs through prolonged or repeated exposure. Hazard(s) not otherwise classified Not Applicable Precautionary statement(s) Prevention P201 Obtain special instructions before use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. www.itwprobrands.com Page 1 continued... CAS No Name P211 Do not spray on an open flame or other ignition source. P251 Pressurized container: Do not pierce or burn, even after use. P260 Do not breathe gas. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves and protective clothing. P261 Avoid breathing gas. P202 Do not handle until all safety precautions have been read and understood. P264 Wash all exposed external body areas thoroughly after handling. Precautionary statement(s) Response P308+P313 IF exposed or concerned: Get medical advice/ attention. P312 Call a POISON CENTER/doctor/physician/first aider/if you feel unwell. P314 Get medical advice/attention if you feel unwell. P302+P352 IF ON SKIN: Wash with plenty of water. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P332+P313 If skin irritation occurs: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. Precautionary statement(s) Storage P405 Store locked up. P410+P403 Protect from sunlight. Store in a well-ventilated place. P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F. P403+P233 Store in a well-ventilated place. Keep container tightly closed. Precautionary statement(s) Disposal P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation. SECTION 3 Composition / information on ingredients Substances See section below for composition of Mixtures Mixtures %[weight] 108-88-3* 10-30 74-98-6.* 10-30 106-97-8. 5-10 64742-47-8* 1-5 67-63-0* 1-5 The specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. SECTION 4 First-aid measures Description of first aid measures Eye Contact If aerosols come in contact with the eyes: Immediately hold the eyelids apart and flush the eye with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. Skin Contact If solids or aerosol mists are deposited upon the skin: Flush skin and hair with running water (and soap if available). Remove any adhering solids with industrial skin cleansing cream. DO NOT use solvents. Seek medical attention in the event of irritation. Inhalation If aerosols, fumes or combustion products are inhaled: Remove to fresh air. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. If breathing is shallow or has stopped, ensure clear airway and apply resuscitation, preferably with a demand valve resuscitator, bag- valve mask device, or pocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor. Ingestion If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than their hips to help avoid possible aspiration ofvomitus. Most important symptoms and effects, both acute and delayed See Section 11 Indication of any immediate medical attention and special treatment needed Toluene* propane butane Petroleum Distillates light* Isopropanol* Part Number: 00516 Version No: 1.5 Page 2 of 11 LPS? Cold Galvanize Issue Date: 01/05/2024 Print Date: 06/05/2024 Continued... Treat symptomatically. SECTION 5 Fire-fighting measures Extinguishing media SMALL FIRE: Water spray, dry chemical or CO2 LARGE FIRE: Water spray or fog. Special hazards arising from the substrate or mixture Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result Special protective equipment and precautions for fire-fighters Fire Fighting -------------------------------------------------------------- GENERAL -------------------------------------------------------------- Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive. Wear breathing apparatus plus protective gloves. Consider evacuation Fight fire from a safe distance, with adequate cover. If safe, switch off electrical equipment until vapour fire hazard removed. Use water delivered as a fine spray to control fire and cool adjacent area. DO NOT approach cylinders suspected to be hot. Cool fire-exposed cylinders with water spray from a protected location. If safe to do so, remove containers from path of fire. -------------------------------------------------------------- FIRE FIGHTING PROCEDURES: -------------------------------------------------------------- The only safe way to extinguish a flammable gas fire is to stop the flow of gas. If the flow cannot be stopped, allow the entire contents of the cylinder to burn while cooling the cylinder and surroundings with water from a suitable distance. Extinguishing the fire without stopping the gas flow may permit the formation of ignitable or explosive mixtures with air. These mixtures may propagate to a source of ignition. -------------------------------------------------------------- SPECIAL HAZARDS -------------------------------------------------------------- Excessive pressures may develop in a gas cylinder exposed in a fire; this may result in explosion. Cylinders with pressure relief devices may release their contents as a result of fire and the released gas may constitute a further source of hazard for the fire-fighter. Cylinders without pressure-relief valves have no provision for controlled release and are therefore more likely to explode if exposed to fire. -------------------------------------------------------------- FIRE FIGHTING REQUIREMENTS: -------------------------------------------------------------- The need for proximity, entry and flash-over protection and special protective clothing should be determined for each incident, by a competent fire-fighting safety professional. Prevent by any means spillage from entering drains or water-courses. Fire/Explosion Hazard Liquid and vapour are highly flammable. Severe fire hazard when exposed to heat or flame. Vapour forms an explosive mixture with air. Severe explosion hazard, in the form of vapour, when exposed to flame or spark. Vapour may travel a considerable distance to source of ignition. Heating may cause expansion or decomposition with violent container rupture. Aerosol cans may explode on exposure to naked flames. Rupturing containers may rocket and scatter burning materials. Hazards may not be restricted to pressure effects. May emit acrid, poisonous or corrosive fumes. On combustion, may emit toxic fumes of carbon monoxide (CO). Combustion products include: carbon monoxide (CO) carbon dioxide (CO2) SECTION 6 Accidental release measures Personal precautions, protective equipment and emergency procedures See section 8 Environmental precautions See section 12 Methods and material for containment and cleaning up Minor Spills Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Wear protective clothing, impervious gloves and safety glasses. Shut off all possible sources of ignition and increase ventilation. Wipe up. If safe, damaged cans should be placed in a container outdoors, away from all ignition sources, until pressure has dissipated. Undamaged cans should be gathered and stowed safely. Personal Protective Equipment advice is contained in Section 8 of the SDS. Part Number: 00516 Version No: 1.5 Page 3 of 11 LPS? Cold Galvanize Issue Date: 01/05/2024 Print Date: 06/05/2024 Continued... + x + x + + + X ? Must not be stored together 0 ? May be stored together with specific preventions + ? May be stored together Source Ingredient Material name TWA STEL Peak Notes SECTION 7 Handling and storage Precautions for safe handling Safe handling Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps. DO NOT enter confined spaces until atmosphere has been checked. Avoid smoking, naked lights or ignition sources. Avoid contact with incompatible materials. When handling, DO NOT eat, drink or smoke. DO NOT incinerate or puncture aerosol cans. DO NOT spray directly on humans, exposed food or food utensils. Avoid physical damage to containers. Always wash hands with soap and water after handling. Work clothes should be laundered separately. Use good occupational work practice. Observe manufacturer's storage and handling recommendations contained within this SDS. Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions are maintained. Other information Keep dry to avoid corrosion of cans. Corrosion may result in container perforation and internal pressure may eject contents of can Store in original containers in approved flammable liquid storage area. DO NOT store in pits, depressions, basements or areas where vapours may be trapped. No smoking, naked lights, heat or ignition sources. Keep containers securely sealed. Contents under pressure. Store away from incompatible materials. Store in a cool, dry, well ventilated area. Avoid storage at temperatures higher than 40 deg C. Store in an upright position. Protect containers against physical damage. Check regularly for spills and leaks. Observe manufacturer's storage and handling recommendations contained within this SDS. Conditions for safe storage, including any incompatibilities Suitable container Aerosol dispenser.Check that containers are clearly labelled. Storage incompatibility Avoid reaction with oxidising agents Compressed gases may contain a large amount of kinetic energy over and above that potentially available from the energy of reaction produced by the gas in chemical reaction with other substances Note: Depending on other risk factors, compatibility assessment based on the table above may not be relevant to storage situations, particularly where large volumes of dangerous goods are stored and handled. Reference should be made to the Safety Data Sheets for each substance or article and risks assessed accordingly. SECTION 8 Exposure controls / personal protection Control parameters Occupational Exposure Limits (OEL) INGREDIENT DATA US OSHA Permissible Exposure Limits (PELs) Table Z-2 Toluene* Toluene 200 ppm 300 ppm 500 (10 min)ppm (Z37.12- 1967) US NIOSH Recommended Exposure Limits (RELs) Toluene* Toluene 100 ppm / 375 mg/m3 560 mg/m3 / 150 ppm Not Available Not Available US OSHA Permissible Exposure Limits (PELs) Table Z-1 propane Propane 1000 ppm / 1800mg/m3 Not Available Not Available Not Available US NIOSH Recommended Exposure Limits (RELs) propane Propane 1000 ppm / 1800 mg/m3 Not Available Not Available Not Available US NIOSH Recommended Exposure Limits (RELs) butane n-Butane 800 ppm / 1900 mg/m3 Not Available Not Available Not Available US OSHA Permissible Exposure Limits (PELs) Table Z-1 Petroleum Distillates light* Oil mist, mineral 5 mg/m3 Not Available Not Available Not Available US OSHA Permissible Exposure Limits (PELs) Table Z-1 Isopropanol* Isopropylalcohol 400 ppm / 980 mg/m3 Not Available Not Available Not Available US NIOSH Recommended Exposure Limits (RELs) Isopropanol* Isopropyl alcohol 400 ppm / 980 mg/m3 1225 mg/m3 / 500 ppm Not Available Not Available Emergency Limits Part Number: 00516 Version No: 1.5 Page 4 of 11 LPS? Cold Galvanize Issue Date: 01/05/2024 Print Date: 06/05/2024 Continued... Ingredient TEEL-1 TEEL-2 TEEL-3 Ingredient Original IDLH Revised IDLH Toluene* Not Available Not Available Not Available propane Not Available Not Available Not Available butane Not Available Not Available Not Available Petroleum Distillates light* 140 mg/m3 1,500 mg/m3 8,900 mg/m3 Isopropanol* 400 ppm 2000* ppm 12000** ppm Toluene* 500 ppm Not Available propane 2,100 ppm Not Available butane Not Available 1,600 ppm Petroleum Distillates light* 2,500 mg/m3 Not Available Isopropanol* 2,000 ppm Not Available Exposure controls Appropriate engineering controls Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. The basic types of engineering controls are: Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard 'physically' away from the worker and ventilation that strategically 'adds' and 'removes' air in the work environment. Ventilation can remove or dilute an air contaminant if designed properly. The design of a ventilation system must match the particular process and chemical or contaminant in use. Employers may need to use multiple types of controls to prevent employee overexposure. General exhaust is adequate under normal conditions. If risk of overexposure exists, wear SAA approved respirator. Correct fit is essential to obtain adequate protection. Provide adequate ventilation in warehouse or closed storage areas. Air contaminants generated in the workplace possess varying 'escape' velocities which, in turn, determine the 'capture velocities' of fresh circulating air required to effectively remove the contaminant. Type of Contaminant: Speed: aerosols, (released at low velocity into zone of active generation) 0.5-1 m/s direct spray, spray painting in shallow booths, gas discharge (active generation into zone of rapid air motion) 1-2.5 m/s (200-500 f/min.) Within each range the appropriate value depends on: Lower end of the range Upper end of the range 1: Room air currents minimal or favourable to capture 1: Disturbing room air currents 2: Contaminants of low toxicity or of nuisance value only. 2: Contaminants of high toxicity 3: Intermittent, low production. 3: High production, heavy use 4: Large hood or large air mass in motion 4: Small hood-local control only Simple theory shows that air velocity falls rapidly with distance away from the opening of a simple extraction pipe. Velocity generally decreases with the square of distance from the extraction point (in simple cases). Therefore the air speed at the extraction point should be adjusted, accordingly, after reference to distance from the contaminating source. The air velocity at the extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min.) for extraction of solvents generated in a tank 2 meters distant from the extraction point. Other mechanical considerations, producing performance deficits within the extraction apparatus, make it essential that theoretical air velocities are multiplied by factors of 10 or more when extraction systems are installed or used. Individual protection measures, such as personal protective equipment Eye and face protection Safety glasses with side shields. Chemical goggles. [AS/NZS 1337.1, EN166 or national equivalent] Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59]. Skin protection See Hand protection below Hands/feet protection No special equipment needed when handling small quantities. OTHERWISE: For potentially moderate exposures: Wear general protective gloves, eg. light weight rubber gloves. For potentially heavy exposures: Wear chemical protective gloves, eg. PVC. and safety footwear. Body protection See Other protection below Other protection No special equipment needed when handling small quantities. OTHERWISE: Overalls. Skin cleansing cream. Eyewash unit. Do not spray on hot surfaces. Respiratory protection Part Number: 00516 Version No: 1.5 Page 5 of 11 LPS? Cold Galvanize Issue Date: 01/05/2024 Print Date: 06/05/2024 Continued... Type AX Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent) Aerosols, in common with most vapours/ mists, should never be used in confined spaces without adequate ventilation. Aerosols, containing agents designed to enhance or mask smell, have triggered allergic reactions in predisposed individuals. SECTION 9 Physical and chemical properties Information on basic physical and chemical properties Appearance Gray Physical state Liquified Gas Relative density (Water = 1) 0.75-0.85 Odour Not Available Partition coefficient n-octanol/ water Not Available Odour threshold Not Available Auto-ignition temperature(?C) Not Available pH (as supplied) Not Available Decompositiontemperature (?C) Not Available Melting point / freezing point (?C) Not Available Viscosity (cSt) Not Available Initial boiling point and boiling range (?C) -44.5 Molecular weight (g/mol) Not Available Flash point (?C) -19 Taste Not Available Evaporation rate Not Available Explosive properties Not Available Flammability HIGHLY FLAMMABLE. Oxidising properties Not Available Upper Explosive Limit (%) 10.9 Surface Tension (dyn/cm ormN/m) Not Available Lower Explosive Limit (%) 1.7 Volatile Component (%vol) Not Available Vapour pressure (kPa) Not Available Gas group Not Available Solubility in water Not Available pH as a solution (1%) Not Available Vapour density (Air = 1) Not Available VOC g/L Not Available SECTION 10 Stability and reactivity Reactivity See section 7 Chemical stability Elevated temperatures. Presence of open flame. Product is considered stable. Hazardous polymerisation will not occur. Possibility of hazardous reactions See section 7 Conditions to avoid See section 7 Incompatible materials See section 7 Hazardous decomposition products See section 5 SECTION 11 Toxicological information Information on toxicological effects Inhaled Inhalation of vapours may cause drowsiness and dizziness. This may be accompanied by sleepiness, reduced alertness, loss of reflexes, lack of co-ordination, and vertigo. The vapour is discomforting WARNING:Intentional misuse by concentrating/inhaling contents may be lethal. The use of a quantity of material in an unventilated or confined space may result in increased exposure and an irritating atmosphere developing. Before starting consider control of exposure by mechanical ventilation. Ingestion Not normally a hazard due to physical form of product. Skin Contact This material can cause inflammation of the skin on contact in some persons. The material may accentuate any pre-existing dermatitis condition Spray mist may produce discomfort Open cuts, abraded or irritated skin should not be exposed to this material Eye Although the material is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may produce transientdiscomfort characterised by tearing or conjunctival redness (as with windburn). Chronic Repeated or long-term occupational exposure is likely to produce cumulative health effects involving organs or biochemical systems. Ample evidence exists from experimentation that reduced human fertility is directly caused by exposure to the material. Ample evidence exists, from results in experimentation, that developmental disorders are directly caused by human exposure to the material. Main route of exposure to the gas in the workplace is by inhalation. Part Number: 00516 Version No: 1.5 Page 6 of 11 LPS? Cold Galvanize Issue Date: 01/05/2024 Print Date: 06/05/2024 Continued... LPS? Cold Galvanize TOXICITY IRRITATION Not Available Not Available Toluene* TOXICITY IRRITATION Dermal (rabbit) LD50: 12124 mg/kg[2] Eye: adverse effect observed (irritating)[1] Inhalation (Rat) LC50: >13350 ppm4h[2] Skin: adverse effect observed (irritating)[1] Oral (Rat) LD50: 636 mg/kg[2] Skin: no adverse effect observed (not irritating)[1] propane TOXICITY IRRITATION Inhalation (Rat) LC50: 364726.819 ppm4h[2] Not Available butane TOXICITY IRRITATION Inhalation (Rat) LC50: 658 mg/l4h[2] Not Available Petroleum Distillates light* TOXICITY IRRITATION Dermal (rabbit) LD50: >2000 mg/kg[2] Eye: no adverse effect observed (not irritating)[1] Inhalation (Rat) LC50: >4.3 mg/l4h[1] Skin: adverse effect observed (irritating)[1] Oral (Rat) LD50: >5000 mg/kg[2] Isopropanol* TOXICITY IRRITATION Dermal (rabbit) LD50: 12800 mg/kg[2] Not Available Inhalation(Mouse) LC50; 53 mg/L4h[2] Oral (Mouse) LD50; 3600 mg/kg[2] Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2. Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances Acute Toxicity Carcinogenicity Skin Irritation/Corrosion Reproductivity Serious Eye Damage/Irritation STOT - Single Exposure Respiratory or Skin sensitisation STOT - Repeated Exposure Mutagenicity Aspiration Hazard Legend: ? Data either not available or does not fill the criteria for classification ? Data available to make classification SECTION 12 Ecological information Toxicity LPS? Cold Galvanize Endpoint Test Duration (hr) Species Value Source Not Available Not Available Not Available Not Available Not Available Toluene* Endpoint Test Duration (hr) Species Value Source EC50 72h Algae or other aquatic plants 12.5mg/L 4 LC50 96h Fish 5-35mg/l 4 EC50 48h Crustacea 3.78mg/L 5 NOEC(ECx) 168h Crustacea 0.74mg/l 2 EC50 96h Algae or other aquatic plants >376.71mg/L 4 propane Endpoint Test Duration (hr) Species Value Source Not Available Not Available Not Available Not Available Not Available butane Endpoint Test Duration (hr) Species Value Source LC50 96h Fish 24.11mg/l 2 EC50(ECx) 96h Algae or other aquatic plants 7.71mg/l 2 EC50 96h Algae or other aquatic plants 7.71mg/l 2 Part Number: 00516 Version No: 1.5 Page 7 of 11 LPS? Cold Galvanize Issue Date: 01/05/2024 Print Date: 06/05/2024 Continued... 14.1. Ingredient Persistence: Water/Soil Persistence: Air Ingredient Bioaccumulation Ingredient Mobility Petroleum Distillates light* Endpoint Test Duration (hr) Species Value Source LC50 96h Fish 2.2mg/L 4 NOEC(ECx) 3072h Fish 1mg/l 1 Isopropanol* Endpoint Test Duration (hr) Species Value Source LC50 96h Fish >1400mg/L 4 EC50(ECx) 24h Algae or other aquatic plants 0.011mg/L 4 EC50 72h Algae or other aquatic plants >1000mg/l 1 EC50 96h Algae or other aquatic plants >1000mg/l 1 EC50 48h Crustacea 7550mg/l 4 Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data DO NOT discharge into sewer or waterways. Persistence and degradability Toluene* LOW (Half-life = 28 days) LOW (Half-life = 4.33 days) propane LOW LOW butane LOW LOW Isopropanol* LOW (Half-life = 14 days) LOW (Half-life = 3 days) Bioaccumulative potential Toluene* LOW (BCF = 90) propane LOW (LogKOW = 2.36) butane LOW (LogKOW = 2.89) Petroleum Distillates light* LOW (BCF = 159) Isopropanol* LOW (LogKOW = 0.05) Mobility in soil Toluene* LOW (Log KOC = 268) propane LOW (Log KOC = 23.74) butane LOW (Log KOC = 43.79) Isopropanol* HIGH (Log KOC = 1.06) SECTION 13 Disposal considerations Waste treatment methods Product / Packaging disposal DO NOT allow wash water from cleaning or process equipment to enter drains. It may be necessary to collect all wash water for treatment before disposal. In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first. Where in doubt contact the responsible authority. Consult State Land Waste Management Authority for disposal. Discharge contents of damaged aerosol cans at an approved site. Allow small quantities to evaporate. DO NOT incinerate or puncture aerosol cans. Bury residues and emptied aerosol cans at an approved site. SECTION 14 Transport information Labels Required Marine Pollutant NO Shipping container, transport vehicle placarding, and labeling may vary from the below information. This depends on the quantity shipped, the applicability of excepted quantity requirements, limited quantity requirements, and/or special provisions according to US DOT, IATA and IMDG regulations. In case of reshipment, it is the responsibility of the shipper to determine the appropriate labels and markings in accordance with applicable transport regulations. Land transport (DOT) UN number or ID number 1950 Part Number: 00516 Version No: 1.5 Page 8 of 11 LPS? Cold Galvanize Issue Date: 01/05/2024 Print Date: 06/05/2024 Continued... 14.2. 14.3. 14.4. 14.5. 14.6. 14.1. 14.2. 14.3. 14.4. 14.5. 14.6. 14.1. 14.2. 14.3. 14.4. 14.5 14.6. Product name Group Product name Ship Type UN proper shipping name Aerosols, flammable, (each not exceeding 1 L capacity) Transport hazard class(es) Class 2.1 Subsidiary Hazard Not Applicable Packing group Not Applicable Environmental hazard Not Applicable Special precautions for user Hazard Label 2.1 Special provisions N82 Air transport (ICAO-IATA / DGR) UN number 1950 UN proper shipping name Aerosols, flammable Transport hazard class(es) ICAO/IATA Class 2.1 ICAO / IATA Subsidiary Hazard Not Applicable ERG Code 10L Packing group Not Applicable Environmental hazard Not Applicable Special precautions for user Special provisions A145 A167 A802 Cargo Only Packing Instructions 203 Cargo Only Maximum Qty / Pack 150 kg Passenger and Cargo Packing Instructions 203 Passenger and Cargo Maximum Qty / Pack 75 kg Passenger and Cargo Limited Quantity Packing Instructions Y203 Passenger and Cargo Limited Maximum Qty / Pack 30 kg G Sea transport (IMDG-Code / GGVSee) UN number 1950 UN proper shipping name AEROSOLS Transport hazard class(es) IMDG Class 2.1 IMDG Subsidiary Hazard Not Applicable Packing group Not Applicable Environmental hazard Not Applicable Special precautions for user EMS Number F-D , S-U Special provisions 63 190 277 327 344 381 959 Limited Quantities 1000 ml 14.7.1. Transport in bulk according to Annex II of MARPOL and the IBC code Not Applicable 14.7.2. Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code Toluene* Not Available propane Not Available butane Not Available Petroleum Distillates light* Not Available Isopropanol* Not Available 14.7.3. Transport in bulk in accordance with the IGC Code Toluene* Not Available propane Not Available butane Not Available Petroleum Distillates light* Not Available Isopropanol* Not Available SECTION 15 Regulatory information Safety, health and environmental regulations / legislation specific for the substance or mixture Toluene* is found on the following regulatory lists Chemical Footprint Project - Chemicals of High Concern List Part Number: 00516 Version No: 1.5 Page 9 of 11 LPS? Cold Galvanize Issue Date: 01/05/2024 Print Date: 06/05/2024 Continued... International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs - Not Classified as Carcinogenic US - California Hazardous Air Pollutants Identified as Toxic Air Contaminants US - California Proposition 65 - Maximum Allowable Dose Levels (MADLs) for Chemicals Causing Reproductive Toxicity US - California Proposition 65 - Reproductive Toxicity US - California Safe Drinking Water and Toxic Enforcement Act of 1986 - Proposition 65 List US - Massachusetts - Right To Know Listed Chemicals US ATSDR Minimal Risk Levels for Hazardous Substances (MRLs) US Clean Air Act - Hazardous Air Pollutants US CWA (Clean Water Act) - List of Hazardous Substances US CWA (Clean Water Act) - Priority Pollutants US CWA (Clean Water Act) - Toxic Pollutants US DOE Temporary Emergency Exposure Limits (TEELs) US Drug Enforcement Administration (DEA) List I and II Regulated Chemicals US EPA Integrated Risk Information System (IRIS) US EPCRA Section 313 Chemical List US NIOSH Recommended Exposure Limits (RELs) US OSHA Permissible Exposure Limits (PELs) Table Z-2 US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory propane is found on the following regulatory lists US - Massachusetts - Right To Know Listed Chemicals US Department of Homeland Security (DHS) - Chemical Facility Anti-Terrorism Standards (CFATS) - Chemicals of Interest US DOE Temporary Emergency Exposure Limits (TEELs) US NIOSH Recommended Exposure Limits (RELs) US OSHA Permissible Exposure Limits (PELs) Table Z-1 US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory butane is found on the following regulatory lists Chemical Footprint Project - Chemicals of High Concern List US - Massachusetts - Right To Know Listed Chemicals US Department of Homeland Security (DHS) - Chemical Facility Anti-Terrorism Standards (CFATS) - Chemicals of Interest US DOE Temporary Emergency Exposure Limits (TEELs) US NIOSH Recommended Exposure Limits (RELs) US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory Petroleum Distillates light* is found on the following regulatory lists Chemical Footprint Project - Chemicals of High Concern List International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs - Group 1: Carcinogenic to humans International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs - Not Classified as Carcinogenic US DOE Temporary Emergency Exposure Limits (TEELs) US National Toxicology Program (NTP) 15th Report Part A Known to be Human Carcinogens US OSHA Permissible Exposure Limits (PELs) Table Z-1 US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory Isopropanol* is found on the following regulatory lists International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs - Not Classified as Carcinogenic US - Massachusetts - Right To Know Listed Chemicals US DOE Temporary Emergency Exposure Limits (TEELs) US EPCRA Section 313 Chemical List US NIOSH Recommended Exposure Limits (RELs) US OSHA Permissible Exposure Limits (PELs) Table Z-1 US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory US TSCA Section 4/12 (b) - Sunset Dates/Status Additional Regulatory Information Not Applicable Federal Regulations Superfund Amendments and Reauthorization Act of 1986 (SARA) Section 311/312 hazard categories Flammable (Gases, Aerosols, Liquids, or Solids) Yes Gas under pressure Yes Explosive No Self-heating No Pyrophoric (Liquid or Solid) No Pyrophoric Gas No Corrosive to metal No Oxidizer (Liquid, Solid or Gas) No Organic Peroxide No Self-reactive No In contact with water emits flammable gas No Combustible Dust No Carcinogenicity No Acute toxicity (any route of exposure) No Reproductive toxicity Yes Part Number: 00516 Version No: 1.5 Page 10 of 11 LPS? Cold Galvanize Issue Date: 01/05/2024 Print Date: 06/05/2024 Continued... Name Reportable Quantity in Pounds (lb) Reportable Quantity in kg CAS No Name This information must be included in all SDSs that are copied and distributed for this material. National Inventory Status Skin Corrosion or Irritation Yes Respiratory or Skin Sensitization No Serious eye damage or eye irritation No Specific target organ toxicity (single or repeated exposure) Yes Aspiration Hazard No Germ cell mutagenicity No Simple Asphyxiant No Hazards Not Otherwise Classified No US. EPA CERCLA Hazardous Substances and Reportable Quantities (40 CFR 302.4) Toluene* 1000 454 US. EPCRA Section 313 Toxic Release Inventory (TRI) (40 CFR 372) This product contains the following EPCRA section 313 chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To- Know-Act of 1986 (40 CFR 372): %[weight] 108-88-3* 10-30 Toluene* 67-63-0* 1-5 Isopropanol* Additional Federal Regulatory Information Not Applicable State Regulations US. California Proposition 65 WARNING: This product can expose you to chemicals including Toluene*, which is known to the State of California to cause birth defects or other reproductive harm. For more information, go to www.P65Warnings.ca.gov Additional State Regulatory Information Not Applicable National Inventory Status Australia - AIIC / Australia Non- Industrial Use Yes Canada - DSL Yes Canada - NDSL No (Toluene*; propane; butane; Petroleum Distillates light*; Isopropanol*) China - IECSC Yes Europe - EINEC / ELINCS / NLP Yes Japan - ENCS Yes Korea - KECI Yes New Zealand - NZIoC Yes Philippines - PICCS Yes USA - TSCA Yes Taiwan - TCSI Yes Mexico - INSQ Yes Vietnam - NCI Yes Russia - FBEPH Yes Legend: Yes = All CAS declared ingredients are on the inventoryNo = One or more of the CAS listed ingredients are not on the inventory. These ingredients may be exempt or will require registration. SECTION 16 Other information Revision Date 01/05/2024 Initial Date 02/05/2024 Other information Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references. The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered. Powered by AuthorITe, from Chemwatch. Part Number: 00516 Version No: 1.5 Page 11 of 11 LPS? Cold Galvanize Issue Date: 01/05/2024 Print Date: 06/05/2024 end of SDS